Beilstein J. Org. Chem.2015,11, 1796–1808, doi:10.3762/bjoc.11.195
cis-cyclooctene because of their substantially different monomer reactivities.
Keywords: cross-metathesis; 1st generation Grubbs’ catalyst; interchangereactions; kinetics; multiblock copolymer; Introduction
A desired sequence of monomer units in a polymer chain can be achieved not only in the
course of polymerization but also through chemical modification of macromolecules [1]. In particular, main-chain polyesters and polyamides are capable of cross-reactions (also known as interchangereactions) characterized by the rearrangement of macromolecular backbones via break up and the formation of
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Graphical Abstract
Figure 1:
Dependences of the (blue) PCOE and (green) PNB mean hydrodynamic radius in CHCl3 on the (a) light ...